f*s
2 楼
haha
f*s
3 楼
姚庆伟 教授
天津大学特聘教授 天津市特聘专家
移动电话：15xxxxxxxxxxx
办公室：022-xxxxxxxxx
Email: x*[email protected]; x**[email protected]
教育背景
l 山西医科大学，学士， 1983
l 山西大学，硕士， 1988
l 伊利诺伊大学－芝加哥分校（Chicago), 博士， 1991
l 哥伦比亚大学（New York), 博士后， 1996－1998
工作经历
l 山西医科大学，助教， 1983－1985
l 山西大学，讲师， 1988－1991
l 北伊利诺伊大学 (DeKalb), 助理教授（tenure track), 1998－2003
l 北伊利诺伊大学 (DeKalb), 副教授（tenured), 2003－2010
研究方向
l 有机合成化学，有机合成方法，过渡金属化学及催化
l 自由基化学，有机反应机理，组合化学
l 绿色有机合成，材料及药物合成化学
代表性论文
1. Qingwei Yao, Mark Zabawa, Joyce Woo, and Chong
Zheng,
“Carbocyclic Carbene Ligands Derived from Aromatic Nitrones: Formation
and
Catalytic Activity of Their Pd(II) Complexes,” J. Am. Chem. Soc. 2007,
129,
3088-3089.
2. Qingwei Yao and Matthew Sheets, “A SeCSe-Pd(II)
Pincer
Complex as a Highly Efficient Catalyst for Allylation of Aldehydes with
Allyltributyltin,” J. Org. Chem. 2006, 71, 5384.
3. Qingwei Yao and Matthew Sheets, “An ionic liquid-
tagged second generation Hoveyda–Grubbs ruthenium carbene complex as
highly
reactive and recyclable catalyst for ring-closing metathesis of di-,
tri-
and tetrasubstituted dienes,” J. Organomet. Chem. 2005, 690, 3577.
4. Qingwei Yao, Elizabeth P. Kinney, and Chong Zheng,
“
Selenium-Ligated Palladium(II) Complexes as Highly Active Catalysts for
Carbon-Carbon Coupling Reactions: The Heck Reaction,” Org. Lett. 2004,
6,
2997.
5. Qingwei Yao and Adalie Rodriguez Motta, “
Immobilization of the Grubbs Second-Generation Ruthenium-Carbene Complex
on
Poly(ethylene glycol): A Highly Reactive and Recyclable Catalysts for
Ring-
Closing and Cross Metathesis,” Tetrahedron Lett. 2004, 45, 2447.
6. Qingwei Yao and Yiliang Zhang, “Poly(fluoroalkyl
acrylate)-Bound Ruthenium Carbene Complex: A Fluorous and Recyclable
Catalyst for Ring-Closing Olefin Metathesis,” J. Am. Chem. Soc. 2004,
126,
74.
7. Qingwei Yao and Yiliang Zhang, “Olefin Metathesis
in
the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluorophosphate Using a
Recyclable Ru Catalyst: Remarkable Effect of a Designer Ionic Tag,”
Angew.
Chem. Int. Ed. 2003, 42, 3395-3398; Angew. Chem. 2003, 115, 3517.
8. Qingwei Yao, Elizabeth P. Kinney and Zhi Yang,
“Ligand
-Free Heck Reaction: Pd(OAc)2 as Active Catalyst Revisited,” J. Org.
Chem.
2003,68, 7528.
9. Qingwei Yao, “OsO4 in Ionic Liquid [Bmim]PF6: A
Recyclable and Reusable Catalyst System for Olefin Dihydroxylation.
Remarkable Effect of DMAP,” Org. Lett. 2002, 2197.
10. Qingwei Yao, “Synthesis of Cyclic Sulfones by Ring-
Closing Metathesis,” Org. Lett. 2002, 4, 427.
11. Qingwei Yao, “Rapid Assembly of Structually Defined
and
Highly Functionalized Conjugated Dienes via Tethered Enyne Metathesis,”
Org
. Lett. 2001, 3, 2069.
12. Arun Singh, Qingwei Yao, Ling Tong, W. Clark Still and
Dalibor Sames, “Combinatorial Approach to the Development of Fluorescent
Sensors for Nanomolar Aqueous Copper,” Tetrahedron Lett. 2000, 41, 9601.
13. Qingwei Yao, “A Soluble Polymer-Bound Ruthenium
Carbene
Complex: A Robust and Reusable Catalyst for Ring-Closing Olefin
Metathesis,
” Angew. Chem. Int. Ed. 2000, 39, 3894-3896. Angew. Chem. 2000, 112,
4060.
14. Martin Newcomb, John H. Horner, Patric O. Whitted,
David
Crich, Qingwei Yao, Hendril Zipse, “b-Phosphatoxyalkyl Radical
Reactions.
Competing Phosphate Migration and Phosphoric Acid Elimination from a
Radical
Cation – Phosphate Anion Pair formed by Heterolytic Fragmentation,” J.
Am
. Chem. Soc. 1999, 121, 10685.
15. Seung-Yong Choi, David Crich, John H. Horner, Xianhai
Huang; Felix N. Martinez, Martin Newcomb, Donald J. Wink and Qingwei
Yao, “
Absence of Diffusively Free Radical Cation Intermediates in Reactions of
b-(
Phosphatoxy)alkyl Radicals,” J. Amer. Chem. Soc. 1998, 120, 211.
16. David Crich and Qingwei Yao, “Free Radical Chemistry
of
Nucleosides and Nucleotides. Ring Opening of C4’-radicals,” Tetrahedron
1998, 54, 305.
17. Athelstan L. J. Beckwith, David Crich, Peter. J.
Duggan
and Qingwei Yao, “Chemistry of b-(Acyloxy)alkyl and b-(Phosphatoxy)alkyl
Radicals, and related Species: Radical and Radical Ionic Migrations and
Fragmentations of Carbon-Oxygen Bonds,” Chem. Rev. 1997, 97, 3273.
18. David Crich and Qingwei Yao, “Generation of Acyl
Radicals
from Thiolesters by Intramolecular Homolytic Substitution at Sulfur,”
J.
Org. Chem. 1996, 61, 3566.
19. David Crich, Xianyun Jiao, Qingwei Yao and John S.
Harwood
, “Radical Clock Reactions under Pseudo-First-Order Conditions Using
Catalytic Quantities of Diphenyl Diselenide. A 77Se- and 119Sn-NMR
Study of
the Reaction of Tributylstannane and Diphenyl Diselenide,” J. Org.
Chem.
1996, 61, 2368.
20. David Crich, Qingwei Yao and G. Fredrick Filzen, “
Chemistry of b-(Phosphatoxy)alkyl and b-(Acyloxy)alkyl Radicals.
Migration
Reactions: Scope and Stereoselectivity of b-(Phosphatoxy)alkyl
Rearrangement
. Mechanism of b-(Phosphatoxy)alkyl and b-(Acyloxy)alkyl Radical
Migration,
” J. Am. Chem. Soc. 1995, 117, 11455.
21. David Crich, Athelstan L. J. Beckwith, Chen Chen,
Qingwei
Yao, Ian G. E. Davison, Robert W. Longmore, Celilia Anaya de Parrodi,
Letica
Quintero-Cortes, and Jesus Sandoval-Ramirez, “Origin of the 'b-Oxygen
Effect' in the Barton Deoxygenation,” J. Am. Chem. Soc. 1995, 117, 8757.
22. David Crich and Qingwei Yao, “Inhibition of
Rearrangements in Stannane-Mediated Radical Reduction Reactions by
Catalytic
Quantities of Diphenyl Diselenide. An Example of Polarity Reversal
Catalysis,” J. Org. Chem. 1995, 60, 84
23. David Crich and Qingwei Yao, “Mechanism of the
Rearrangement of 2-(Vinyloxy)alkyl to 4-Ketobutyl Radicals,” Tetrahedron
1994, 50, 12305.
24. Jarmila Brunckova, David Crich and Qingwei Yao, “
Intramolecular Hydrogen Atom Abstraction in Carbohydrates and
Nucleosides;
Inversion of a- to b-Mannopyranosides and Generation of Thymidine C-4'
Radicals,” Tetrahedron Lett. 1994, 35, 6619.
25. David Crich and Qingwei Yao, “b-(Phosphatoxy)alkyl and
b-
(Acyloxy)alkylRadical Rearrangements: Evidence for Nondissociative
Mechanisms,” J. Am. Chem. Soc. 1994, 116, 2631.
26. David Crich and Qingwei Yao, “A New C-C Bond-forming
Free
Radical Rearrangement,” J. Chem. Soc., Chem. Comm. 1993, 1265.
27. David Crich and Qingwei Yao, “The b-(Phosphatoxy)alkyl
Radical Rearrangement. A Stereochemical Probe,” Tetrahedron Lett. 1993,
34
, 5677.
28. David Crich and Qingwei Yao, “The b-
(Phosphonooxy)alkyl
Radical Rearrangement,” J. Am. Chem. Soc. 1993, 115, 1165.
天津大学特聘教授 天津市特聘专家
移动电话：15xxxxxxxxxxx
办公室：022-xxxxxxxxx
Email: x*[email protected]; x**[email protected]
教育背景
l 山西医科大学，学士， 1983
l 山西大学，硕士， 1988
l 伊利诺伊大学－芝加哥分校（Chicago), 博士， 1991
l 哥伦比亚大学（New York), 博士后， 1996－1998
工作经历
l 山西医科大学，助教， 1983－1985
l 山西大学，讲师， 1988－1991
l 北伊利诺伊大学 (DeKalb), 助理教授（tenure track), 1998－2003
l 北伊利诺伊大学 (DeKalb), 副教授（tenured), 2003－2010
研究方向
l 有机合成化学，有机合成方法，过渡金属化学及催化
l 自由基化学，有机反应机理，组合化学
l 绿色有机合成，材料及药物合成化学
代表性论文
1. Qingwei Yao, Mark Zabawa, Joyce Woo, and Chong
Zheng,
“Carbocyclic Carbene Ligands Derived from Aromatic Nitrones: Formation
and
Catalytic Activity of Their Pd(II) Complexes,” J. Am. Chem. Soc. 2007,
129,
3088-3089.
2. Qingwei Yao and Matthew Sheets, “A SeCSe-Pd(II)
Pincer
Complex as a Highly Efficient Catalyst for Allylation of Aldehydes with
Allyltributyltin,” J. Org. Chem. 2006, 71, 5384.
3. Qingwei Yao and Matthew Sheets, “An ionic liquid-
tagged second generation Hoveyda–Grubbs ruthenium carbene complex as
highly
reactive and recyclable catalyst for ring-closing metathesis of di-,
tri-
and tetrasubstituted dienes,” J. Organomet. Chem. 2005, 690, 3577.
4. Qingwei Yao, Elizabeth P. Kinney, and Chong Zheng,
“
Selenium-Ligated Palladium(II) Complexes as Highly Active Catalysts for
Carbon-Carbon Coupling Reactions: The Heck Reaction,” Org. Lett. 2004,
6,
2997.
5. Qingwei Yao and Adalie Rodriguez Motta, “
Immobilization of the Grubbs Second-Generation Ruthenium-Carbene Complex
on
Poly(ethylene glycol): A Highly Reactive and Recyclable Catalysts for
Ring-
Closing and Cross Metathesis,” Tetrahedron Lett. 2004, 45, 2447.
6. Qingwei Yao and Yiliang Zhang, “Poly(fluoroalkyl
acrylate)-Bound Ruthenium Carbene Complex: A Fluorous and Recyclable
Catalyst for Ring-Closing Olefin Metathesis,” J. Am. Chem. Soc. 2004,
126,
74.
7. Qingwei Yao and Yiliang Zhang, “Olefin Metathesis
in
the Ionic Liquid 1-Butyl-3-methylimidazolium Hexafluorophosphate Using a
Recyclable Ru Catalyst: Remarkable Effect of a Designer Ionic Tag,”
Angew.
Chem. Int. Ed. 2003, 42, 3395-3398; Angew. Chem. 2003, 115, 3517.
8. Qingwei Yao, Elizabeth P. Kinney and Zhi Yang,
“Ligand
-Free Heck Reaction: Pd(OAc)2 as Active Catalyst Revisited,” J. Org.
Chem.
2003,68, 7528.
9. Qingwei Yao, “OsO4 in Ionic Liquid [Bmim]PF6: A
Recyclable and Reusable Catalyst System for Olefin Dihydroxylation.
Remarkable Effect of DMAP,” Org. Lett. 2002, 2197.
10. Qingwei Yao, “Synthesis of Cyclic Sulfones by Ring-
Closing Metathesis,” Org. Lett. 2002, 4, 427.
11. Qingwei Yao, “Rapid Assembly of Structually Defined
and
Highly Functionalized Conjugated Dienes via Tethered Enyne Metathesis,”
Org
. Lett. 2001, 3, 2069.
12. Arun Singh, Qingwei Yao, Ling Tong, W. Clark Still and
Dalibor Sames, “Combinatorial Approach to the Development of Fluorescent
Sensors for Nanomolar Aqueous Copper,” Tetrahedron Lett. 2000, 41, 9601.
13. Qingwei Yao, “A Soluble Polymer-Bound Ruthenium
Carbene
Complex: A Robust and Reusable Catalyst for Ring-Closing Olefin
Metathesis,
” Angew. Chem. Int. Ed. 2000, 39, 3894-3896. Angew. Chem. 2000, 112,
4060.
14. Martin Newcomb, John H. Horner, Patric O. Whitted,
David
Crich, Qingwei Yao, Hendril Zipse, “b-Phosphatoxyalkyl Radical
Reactions.
Competing Phosphate Migration and Phosphoric Acid Elimination from a
Radical
Cation – Phosphate Anion Pair formed by Heterolytic Fragmentation,” J.
Am
. Chem. Soc. 1999, 121, 10685.
15. Seung-Yong Choi, David Crich, John H. Horner, Xianhai
Huang; Felix N. Martinez, Martin Newcomb, Donald J. Wink and Qingwei
Yao, “
Absence of Diffusively Free Radical Cation Intermediates in Reactions of
b-(
Phosphatoxy)alkyl Radicals,” J. Amer. Chem. Soc. 1998, 120, 211.
16. David Crich and Qingwei Yao, “Free Radical Chemistry
of
Nucleosides and Nucleotides. Ring Opening of C4’-radicals,” Tetrahedron
1998, 54, 305.
17. Athelstan L. J. Beckwith, David Crich, Peter. J.
Duggan
and Qingwei Yao, “Chemistry of b-(Acyloxy)alkyl and b-(Phosphatoxy)alkyl
Radicals, and related Species: Radical and Radical Ionic Migrations and
Fragmentations of Carbon-Oxygen Bonds,” Chem. Rev. 1997, 97, 3273.
18. David Crich and Qingwei Yao, “Generation of Acyl
Radicals
from Thiolesters by Intramolecular Homolytic Substitution at Sulfur,”
J.
Org. Chem. 1996, 61, 3566.
19. David Crich, Xianyun Jiao, Qingwei Yao and John S.
Harwood
, “Radical Clock Reactions under Pseudo-First-Order Conditions Using
Catalytic Quantities of Diphenyl Diselenide. A 77Se- and 119Sn-NMR
Study of
the Reaction of Tributylstannane and Diphenyl Diselenide,” J. Org.
Chem.
1996, 61, 2368.
20. David Crich, Qingwei Yao and G. Fredrick Filzen, “
Chemistry of b-(Phosphatoxy)alkyl and b-(Acyloxy)alkyl Radicals.
Migration
Reactions: Scope and Stereoselectivity of b-(Phosphatoxy)alkyl
Rearrangement
. Mechanism of b-(Phosphatoxy)alkyl and b-(Acyloxy)alkyl Radical
Migration,
” J. Am. Chem. Soc. 1995, 117, 11455.
21. David Crich, Athelstan L. J. Beckwith, Chen Chen,
Qingwei
Yao, Ian G. E. Davison, Robert W. Longmore, Celilia Anaya de Parrodi,
Letica
Quintero-Cortes, and Jesus Sandoval-Ramirez, “Origin of the 'b-Oxygen
Effect' in the Barton Deoxygenation,” J. Am. Chem. Soc. 1995, 117, 8757.
22. David Crich and Qingwei Yao, “Inhibition of
Rearrangements in Stannane-Mediated Radical Reduction Reactions by
Catalytic
Quantities of Diphenyl Diselenide. An Example of Polarity Reversal
Catalysis,” J. Org. Chem. 1995, 60, 84
23. David Crich and Qingwei Yao, “Mechanism of the
Rearrangement of 2-(Vinyloxy)alkyl to 4-Ketobutyl Radicals,” Tetrahedron
1994, 50, 12305.
24. Jarmila Brunckova, David Crich and Qingwei Yao, “
Intramolecular Hydrogen Atom Abstraction in Carbohydrates and
Nucleosides;
Inversion of a- to b-Mannopyranosides and Generation of Thymidine C-4'
Radicals,” Tetrahedron Lett. 1994, 35, 6619.
25. David Crich and Qingwei Yao, “b-(Phosphatoxy)alkyl and
b-
(Acyloxy)alkylRadical Rearrangements: Evidence for Nondissociative
Mechanisms,” J. Am. Chem. Soc. 1994, 116, 2631.
26. David Crich and Qingwei Yao, “A New C-C Bond-forming
Free
Radical Rearrangement,” J. Chem. Soc., Chem. Comm. 1993, 1265.
27. David Crich and Qingwei Yao, “The b-(Phosphatoxy)alkyl
Radical Rearrangement. A Stereochemical Probe,” Tetrahedron Lett. 1993,
34
, 5677.
28. David Crich and Qingwei Yao, “The b-
(Phosphonooxy)alkyl
Radical Rearrangement,” J. Am. Chem. Soc. 1993, 115, 1165.
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